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This article examines the science, performance, and deployment of fire-blocking gels used for structure protection in wildfire-prone areas. Covering key formulations like Barricade, Thermo-Gel, and Ember Bloc, it explains how superabsorbent polymer gels cling to surfaces, insulate structures from heat and flame, and provide temporary fire resistance for 24–48 hours. Methods of application, product comparisons, environmental impacts, and regulatory status are discussed, along with case studies of successful deployments. The guide is ideal for homeowners, emergency managers, and fire professionals looking to integrate active wildfire defense measures.